Akl M. Awwad
Abstract
Silver/ silver chloride (Ag/AgCl-NPs) nanoparticles were synthesized by a simple procedure using Albizia julibrissin flowers extract. The flowers of Albizia julibrissin extract acts a reducing, chlorinated and capping agent in the formation of Ag/AgCl-NPs. UV-visible spectroscopy was used to monitor ...
Read More
Silver/ silver chloride (Ag/AgCl-NPs) nanoparticles were synthesized by a simple procedure using Albizia julibrissin flowers extract. The flowers of Albizia julibrissin extract acts a reducing, chlorinated and capping agent in the formation of Ag/AgCl-NPs. UV-visible spectroscopy was used to monitor the quantitative formation of silver/ silver chloride nanoparticles. For complete conversion of silver ions to silver/ silver chloride nanoparticles, time of reaction is less than 5 min at temperature 80 o C and 24h in dark conditions at room temperature. The synthesized Ag/AgCl-NPs nanoparticles were characterized with X-ray diffraction (XRD), UV-vis Spectroscopy, scanning electron microscopy (SEM) and Fourier transforms infrared spectroscopy (FT-IR). UV-visible absorption studies revealed surface plasmon resonance (SPR) peak around 410-430 nm, confirming the presence of Ag/AgCl nanoparticles. The average particle size ranged from 5-20 nm. The particle size could be controlled by changing the flowers extract, silver ion concentration and temperature. FT-IR spectra of flowers extract before and after the synthesis of silver/ silver chloride nanoparticles were determined to allow identification of possible functional groups responsible for the reduction of silver ions to silver/silver chloride nanoparticles.
Akl M. Awwad; Nidá M. Salem; Amany O. Abdeen
Abstract
Sulfur nanoparticles have been successfully prepared from sodium thiosulfate in the presence of Albizia julibrissin fruits extract at room temperature. The resulting sulfur nanoparticles were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron ...
Read More
Sulfur nanoparticles have been successfully prepared from sodium thiosulfate in the presence of Albizia julibrissin fruits extract at room temperature. The resulting sulfur nanoparticles were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). XRD characterizes the final product as highly crystalline sulfur, exhibited high purity, spherical shape with average particle size of about 20 nm, and particle size distribution in range 10 nm to 100 nm. The particle size of nanoparticles could be controlled by tuning the amount of Albizia julibrissin fruits extract. FT-IR analysis of S-NPs indicated a new chemistry linkage on the surface of sulfur nanoparticles. This suggests that Albizia julibrissin fruits extract can bind to sulfur nanoparticles through carbonyl of the amino acid residues in the protein of the extracts, therefore acting as stabilizer and dispersing agent for synthesized sulfur nanoparticles. This research provides a greener and more environment-friendly synthetic method for the production of sulfur nanoparticles for antibacterial and antifungal activities.
Akl M. Awwad; Borhan Albiss
Abstract
Copper hydroxide nanowires were synthesized from copper chloride dihydrate and sodium hydroxide in the presence of Pistachio leaf extract at room temperature. The results of scanning electron microscopy (SEM) exhibited that the copper hydroxide Cu(OH)2 are nanowires ...
Read More
Copper hydroxide nanowires were synthesized from copper chloride dihydrate and sodium hydroxide in the presence of Pistachio leaf extract at room temperature. The results of scanning electron microscopy (SEM) exhibited that the copper hydroxide Cu(OH)2 are nanowires in shape and having an average diameter of ca. 10 nm and lengths of up to 500 nm . The Fourier transfor infrared spectroscopy (FT-IR) results examined the bioactive functional groups , which acts as dispersing, binding and capping agent for the copper hydroxide nanowires. X-ray diffraction (XRD) spectra confirmed the copper hydroxide nanoparticles crystalline in nature. The current research introduces a new, simple, and rapid route for the in –laboratory synthesis of copper hydroxide nanowires. This facile and green approach may provide a useful tool to large scale synthesis other copper nanoparticles that have potential biotechnology.
Akl M. Awwad; Borhan Albiss; Ahmad L. Ahmad
Abstract
In this paper, a green method is reported for synthesis and characterization of zinc oxide nanosheets using Olea europea leaf extract. ZnO nanosheets were characterized by UV-vis absorption spectroscopy, Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy ...
Read More
In this paper, a green method is reported for synthesis and characterization of zinc oxide nanosheets using Olea europea leaf extract. ZnO nanosheets were characterized by UV-vis absorption spectroscopy, Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The UV-vis absorption spectrum shows an absorption band at 374 nm due to ZnO nanosheets. XRD characterize the final product as highly crystalline ZnO with sizes in the range 18-30 nm. The SEM results reveal a presence of network of randomly oriented ZnO nanosheets or nanoplatelets with an average size of 500 nm and thicknesses of about 20 nm. This facile and green approach may provide a useful tool to large scale synthesis other nanoparticles that have potential biotechnology.
Akl M. Awwad; Nida M. Salem; Ammany O. Abdeen
Abstract
This paper reports a rapid and eco-friendly green method for synthesis of silver nanoparticles from silver nitrate solution using loquat leaf extract. Effect the amount of leaf extract, reaction time, silver nitrate concentration and temperature were investigated. Biosynthesized silver nanoparticles ...
Read More
This paper reports a rapid and eco-friendly green method for synthesis of silver nanoparticles from silver nitrate solution using loquat leaf extract. Effect the amount of leaf extract, reaction time, silver nitrate concentration and temperature were investigated. Biosynthesized silver nanoparticles (AgNPs) were characterized by X-ray diffraction (XRD), atomic absorption spectroscopy (AAS) and Fourier transform infrared spectroscopy (FT-IR). UV-vis spectroscopy showed that the surface plasmon resonance (SPR) at 425 nm. The structural peaks in XRD pattern and average crystalline size around 18 nm clearly illustrates that AgNPs synthesized by our green method were nanocrystalline in nature with face centered cubic geometry. The antibacterial activity of biosynthesized silver nanoparticles showed effective inhibitory activity against water borne pathogens, Shegella and Listeria bacteria.
