Document Type : Research Article
Authors
- Prateek Vasudeo Sawant 1
- Mahadev Agatrao Parekar 1
- Avadhut Vasudev Kardile 1
- Yogesh B. Khollam 2
- Latesh Khanderao Nikam 1
- Ravindra Udayrao Mene 1
1 Department of Physics, PDEA’s Annasaheb Magar Mahavidyalaya, Hadapsar, Pune 411028, Maharashtra, India
2 Department of Physics, PDEA’s Baburaoji Gholap College, Sangvi, Pune 411027, Maharashtra, India
Abstract
This research explores the influence of hydrothermal reaction time on the structural, optical and morphological properties of TiO2 nanoparticles. The photocatalytic performance of TiO2 nanoparticles for the degradation of Methylene Blue is also evaluated and a co-relation between reaction time and photocatalytic efficiency is established. Structural analysis reveals well-defined anatase phases with enhanced crystallinity at extended reaction times. UV-Visible spectroscopy demonstrates a red shift in absorption with increased reaction time, indicative of tuneable optical properties. FE-SEM images show an increase in particle agglomeration with increasing hydrothermal duration. Photocatalytic experiments underline TiO2-12 as the most efficient catalyst, achieving a remarkable 97% degradation within 105 minutes. The Langmuir-Hinshelwood kinetics model elucidates the reaction rate dependence on hydrothermal reaction time, emphasizing the role of synthesis parameters on the photocatalytic activity of TiO2. Moreover, TiO2-12 sample shows an enhanced degradation rate compared to other samples. Based on the findings, a possible mechanism of photocatalytic degradation of Methylene Blue is proposed.
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