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Conjugate-like addition of soft nucleophiles to 8-alkenylBODIPYs

    Enrique Alvarado-Martínez Eduardo Peña-Cabrera

Advanced Materials Letters, 2018, Volume 9, Issue 6, Pages 426-431
10.5185/amlett.2018.1859

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Abstract

Meso-phenylethenylBODIPY 8 was prepared using the Liebeskind-Srogl cross-coupling reaction. The reactivity of 8 was evaluated in the addition of soft nucleophiles observing that, in all the cases studied, the addition took place exclusively at the b-alkene position with good chemical yields under mild conditions. While the starting BODIPY 8 was non-emissive, all of the adducts were highly fluorescent in MeOH, except for meso-coumarinBODIPY 11. However, when the fluorescence of 11 was measured in EtOAc, a 41-fold increase was observed. This behaviour was explained in terms of a photoinduced electron-transfer phenomenon. 
Keywords:
    BODIPY meso alkenylBODIPY conjugate addition Fluorescence
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(2018). Conjugate-like addition of soft nucleophiles to 8-alkenylBODIPYs. Advanced Materials Letters, 9(6), 426-431. doi: 10.5185/amlett.2018.1859
Enrique Alvarado-Martínez; Eduardo Peña-Cabrera. "Conjugate-like addition of soft nucleophiles to 8-alkenylBODIPYs". Advanced Materials Letters, 9, 6, 2018, 426-431. doi: 10.5185/amlett.2018.1859
(2018). 'Conjugate-like addition of soft nucleophiles to 8-alkenylBODIPYs', Advanced Materials Letters, 9(6), pp. 426-431. doi: 10.5185/amlett.2018.1859
Conjugate-like addition of soft nucleophiles to 8-alkenylBODIPYs. Advanced Materials Letters, 2018; 9(6): 426-431. doi: 10.5185/amlett.2018.1859
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