We report the thermal annealing effect of ZnO-SnO2 composite thin films deposited by pulsed laser deposition on its structural, electrical, and optical properties. The results present a consistent portrayal of the evolution of ZnO-SnO2 composite oxide films phase formation in post-annealed condition and its subsequent effect on various physical properties. X-ray diffraction confirms that the films transform from nearly amorphous to fully crystalline state on thermal annealing at 600 °C. X-ray photoelectron spectroscopy reveals a small shift in Sn-3d peak towards lower energy and O-1s and Zn-2p < /em> peaks towards higher binding energy with increasing ZnO concentration and confirms the formation of combined oxides of ZnO and SnO2. The average optical transmission is greater than 80 % in the visible region of the annealed ZnO-SnO2 composite films. The lowest electrical resistivity of 9.8 × 10 -4 Ωcm has been obtained in the film containing 25 wt % ZnO. Our results suggest that annealed ZnO-SnO2 composite films with improved electrical and optical properties could find potential use in thin film solar cells or touch pad control panels.