Ghimire Prateek; Yulin Wang; Henggan Li; Yuanfu Ban; Hao Luo; Danping Lin; Jinglong Yang; Shuyan Lin; Zhengyang Pan; Qingwei Su
Abstract
The purpose of this study is to analyse the effective method of dispersion of MWCNTs for the application in cement-based composites. Efficient dispersion of Carbon Nanotubes (CNTs) is one of the most challenging and crucial aspects for the application in cement-based composite. In this study, two different ...
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The purpose of this study is to analyse the effective method of dispersion of MWCNTs for the application in cement-based composites. Efficient dispersion of Carbon Nanotubes (CNTs) is one of the most challenging and crucial aspects for the application in cement-based composite. In this study, two different CNTs, pristine and functionalized (p-MWCNTs and f-MWCNTs) were dispersed in de-ionized water using different surfactants, Polyvinylpyrrolidone (PVP k-30 and PVP k-90) & Sodium Dodecyl Sulfate (SDS) and conducted a comparative investigation of the effects. Dispersion using an ultrasonic, treatment with surfactant and integrated method of both were analysed. The influence of CNTs dispersion on the electrical conductivity of the aqueous solution and to cement composites has been studied. Among the surfactant used PVPk-30 provide the best-dispersing effect while PVPk-30+SDS shows an extraordinary enhancement of conductivity of an aqueous solution. Analysis of electrical conductivity of Various % CNTs’ loaded specimen (0,0.001,0.003,0.025 wt.%) with different curing period (3,7,14,21,28 days) showed that the electrical resistivity decreases with CNTs’ loading. Dispersion effect of surfactant on p-MWCNTs and f-MWCNTs has been characterized by Ultraviolet-visible Spectroscopy (UV-Vis) and electrical resistivity measurement is carried for investigation and comparison on enhancement of electrical conductivity.
Bhanu Pratap Singh; Veena Choudhary; Satish Teotia; Tejendra Kumar Gupta; Vidya Nand Singh; Sanjay Rangnath Dhakate; Rakesh Behari Mathur
Abstract
Dispersion of multiwalled carbon nanotubes (MWCNTs) into epoxy resin is a challenging task for the process to be viable on industrial scale. Herein, amine functionalized MWCNTs (Am-MWCNTs) were reinforced into epoxy resin using industrially viable, fast, efficient, solvent free, high speed homogenizer ...
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Dispersion of multiwalled carbon nanotubes (MWCNTs) into epoxy resin is a challenging task for the process to be viable on industrial scale. Herein, amine functionalized MWCNTs (Am-MWCNTs) were reinforced into epoxy resin using industrially viable, fast, efficient, solvent free, high speed homogenizer dispersion technique. Am-MWCNTs ranging from 0.1 to 0.75% by w/w were loaded in epoxy and the effects of loading of Am-MWCNTs on mechanical properties of epoxy composites are investigated. The flexural strength of Am-MWCNTs based epoxy composites reached up to 163 MPa for 0.5 wt% MWCNTs loaded sample compared to 95 MPa for pure cured epoxy sample; an overall improvement of 72% in the flexural strength. In addition to this, the flexural modulus value reached to 3795 MPa for 0.75 wt% Am-MWCNTs loaded sample from 2250 MPa for pure epoxy sample, an improvement of 69%. The enhancement in the mechanical properties was correlated with the dynamic scanning calorimeter results, TEM and SEM images of fractured surface. The substantial improvement in the mechanical properties of the epoxy resin at such low CNT loading can open a venue for the preparation of structurally strong structures for aerospace, defence, automobile and sports industries.
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