Angélica M. Giorgi Perez; Marisol Fernández Rojas; Luz A. Carreño Díaz
Abstract
Industrial combustion of fuels containing sulfur is responsible for most of the greenhouse gases in the atmosphere. The high impact of fuels is mainly on the content of aromatic S-compounds. These compounds are hard to remove through conventional hydrodesulphurization (HDS) processes because of their ...
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Industrial combustion of fuels containing sulfur is responsible for most of the greenhouse gases in the atmosphere. The high impact of fuels is mainly on the content of aromatic S-compounds. These compounds are hard to remove through conventional hydrodesulphurization (HDS) processes because of their refractory properties and high boiling points. In this research, we are reporting the preparation, characterization, and evaluation of a cheap, regenerable and reusable composite based on the ionic liquid 1-butyl-3-methylimidazolium chloride immobilized on a renewable matrix of natural cellulose fibers. Characterization of the composite included FTIR, TGA, SEM, and XDR. The extraction capacity of thiophene and benzothiophene of the synthesized material was evaluated in synthetic mixes in isooctane and monitored by GC-FID. We achieved removal percentages of up to 62% of total sulfur from a model oil with an initial concentration of 458 mg S/L.
![Ionic liquid [BMIM][Cl] immobilized on cellulose fibers from pineapple leaves for desulphurization of fuels](data/aml/coversheet/261655353119.jpg)
Misael D. Cogollo Valdes; Magda A. Salazar Vega; Melissa J. Cely Pinto; Ana M. Pinilla Torres; Jessica V. Ardila Antolínez; Marisol Fernández Rojas; Luz A. Carreño Diaz*
Abstract
Environmental consequences of high consumption of fossil fuels containing sulfur compounds have promoted research in technologies for their removal. Catalytic hydrodesulphurization currently used requires high temperature and pressure. Alternative technologies based on ionic liquids pure and anchored ...
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Environmental consequences of high consumption of fossil fuels containing sulfur compounds have promoted research in technologies for their removal. Catalytic hydrodesulphurization currently used requires high temperature and pressure. Alternative technologies based on ionic liquids pure and anchored to matrices have shown good desulfurization properties. Composites offer advantages of reuse, less time consuming and costs, using lower IL amount. In this work, we obtained a solid composite containing [BMIM][BF4] supported on oxidized active carbon and characterized by FTIR, BET, TGA-DSC, and SEM. We evaluated the extraction capacity of benzothiophene, thiophene, dibenzothiophene, and diphenyl sulphide from a model fuel with both pure [BMIM][BF4] as well as the same IL on oxidized activated carbon. In the extraction process using pure IL were achieved removal percentages of up to 69.8% whereas with the composite it was possible to reduce 80 % of the sulfur content.
